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Soil remediation time to achieve clean-up goals II: influence of natural organic matter and water contents

机译:实现修复目标的土壤修复时间II:天然有机物和水分的影响

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摘要

This work reports a relatively rapid procedure for the forecasting of the remediation time (RT) of sandy soils contaminated withcyclohexane using vapour extraction. The RT estimated through the mathematical fitting of experimental results was compared with thatof real soils. The main objectives were: (i) to predict the RT of soils with natural organic matter (NOM) and water contents different fromthose used in experiments; and (ii) to analyse the time and efficiency of remediation, and the distribution of contaminants into the soilmatrix after the remediation process, according to the soil contents of: (ii1) NOM; and (ii2) water. For sandy soils with negligible claycontents, artificially contaminated with cyclohexane before vapour extraction, it was concluded that: (i) if the NOM and water contentsbelonged to the range of the prepared soils, the RT of real soils could be predicted with relative differences not higher than 12%; (ii1) theincrease of NOM content from 0% to 7.5% increased the RT (1.8–13 h) and decreased the remediation efficiency (RE) (99–90%) and (ii2)the increase of soil water content from 0% to 6% increased the RT (1.8–4.9 h) and decreased the RE (99–97%). NOM increases the monolayercapacity leading to a higher sorption into the solid phase. Increasing of soil water content reduces the mass transfer coefficientbetween phases. Concluding, NOM and water contents influence negatively the remediation process, turning it less efficient and moretime consuming, and consequently more expensive.
机译:这项工作报告了相对较快的程序,用于通过蒸气萃取来预测被环己烷污染的沙质土壤的修复时间(RT)。通过对实验结果进行数学拟合得出的RT与实际土壤进行了比较。主要目标是:(i)预测天然有机物(NOM)和含水量与实验所用土壤不同的土壤的RT; (ii)根据以下内容分析土壤的修复时间和效率,以及修复过程后污染物进入土壤基质的分布:(ii1)NOM; (ii2)水。对于在粘土含量可忽略的砂质土壤,在抽汽之前被环己烷人工污染,得出以下结论:(i)如果NOM和水分含量在准备好的土壤范围内,则可以预测真实土壤的RT,相对差异不高超过12%; (ii1)NOM含量从0%增加到7.5%,从而增加了RT(1.8–13 h)并降低了修复效率(RE)(99–90%),并且(ii2)土壤水分从0%增加到了6%的患者增加了放疗时间(1.8–4.9小时),而RE降低了(99–97%)。 NOM增加了单层容量,导致更高的固相吸附率。土壤含水量的增加会降低各相之间的传质系数。最后,NOM和水含量会对修复过程产生负面影响,使其效率降低,耗时更多,因此价格更高。

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